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In the film he plays Scott Smith, the boyfriend of Harvey Milk (Penn).
Kenneth Turan of the Los Angeles Times, in review of the film, wrote: "Franco is a nice match for him [Penn] as the lover who finally has enough of political life".
Franco is known for his roles in live-action films, such as Sam Raimi's Spider-Man trilogy (2002–2007); Milk (2008); Pineapple Express (2008); Eat, Pray, Love (2010); Rise of the Planet of the Apes (2011); Spring Breakers (2012); Oz the Great and Powerful (2013); This Is the End (2013); and The Disaster Artist (2017), for which he won a Golden Globe Award for Best Actor.
He is known for his collaborations with fellow actor Seth Rogen, having appeared in eight films and one television series with him.
Also in 2006, he made a cameo appearance in the romantic comedy The Holiday.
Franco co-starred with Sienna Miller in the low-budget independent film Camille, a dark fantasy dramedy about a young newlywed couple and Interview, where he appears in a voice only role, both 2007 movies that were ignored by audiences and critics alike.
Franco volunteers for the Art of Elysium charity, and has taught film classes at New York University, the University of Southern California, UCLA, Studio 4, Palo Alto High School, and Playhouse West.
While working at the establishment, he would practice accents on customers, an experience he remembered nostalgically in a 2015 Washington Post editorial titled "Mc Donald's was there for me when no one else was". James Dean." Despite already being a fan of Dean, Franco feared he might be typecast if he'd captured the actor too convincingly.
To prepare for his role, he met with sex workers or people who had previously been prostitutes.
In her New York Times review, critic Manohla Dargis wrote: "He's delightful as Saul, loosey-goosey and goofy yet irrepressibly sexy, despite that greasy curtain of hair and a crash pad with a zero WAF (Woman Acceptance Factor).
It's an unshowy, generous performance and it greatly humanizes a movie that, as it shifts genre gears and cranks up the noise, becomes disappointingly sober and self-serious".
Franco began 2010 by making an appearance on the sitcom 30 Rock where he played himself and carried on a fake romance with Jenna Maroney (Jane Krakowski) in a scheme concocted by their respective agents.
127 Hours centered on Ralston trying to free his hand after it became trapped under a boulder in a ravine while canyoneering alone in Utah and resorting to desperate measures in order to survive, eventually amputating his arm.